Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 minutes. It is a moderately volatile colourless liquid with an unpleasant acrid odour. It is toxic, reacts with water, and is also listed under the Chemical Weapons Convention as it may be used for the production of chemical weapons. 0000008223 00000 n The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). 0000010294 00000 n It reacts with water to liberate the toxic gases HCl and SO 2 . Safety considerations of lithium-thionyl chloride cells The use of spirally wound lithium-thionyl chloride (Li-SOCl2) cells is currently limited because of their hazardous behavior. Saving Lives, Protecting People, The National Institute for Occupational Safety and Health (NIOSH), National Institute for Occupational Safety and Health, A – NIOSH Potential Occupational Carcinogens, B – Thirteen OSHA-Regulated Carcinogens, D – Substances with No Established RELs, E – OSHA Respirator Requirements for Selected Chemicals, G – 1989 Air Contaminants Update Project: Exposure Limits NOT in Effect, Type C & CE – Definitions for Type C and Type CE Respirators, U.S. Department of Health & Human Services. It is a moderately volatile colourless liquid with an unpleasant acrid odour. %PDF-1.5 %���� Thionyl chloride is an inorganic compound with the chemical formula SOCl 2. The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. Thionyl Chloride CAS No 7719-09-7 MATERIAL SAFETY DATA SHEET SDS/MSDS. * Breathing Thionyl Chloride can irritate the lungs causing <<1b2552d1b1366e49b0bd9b0d50bc0452>]>> 0000001311 00000 n Since most reactions using SOCl 2 evolve these gases, they should be performed only in well‐ventilated hoods. 0000009613 00000 n 13 - DISPOSAL CONSIDERATIONS Dispose in accordance with applicable regulations which vary from country to country. 0000017598 00000 n Prevention. Applicable part number: GAP-9419-H THAAD KVB . 0000000016 00000 n Use only outdoors or in a well-ventilated area. SECTION 2- HAZARD(S) IDENTIFICATION Classification: The batteries described in this SDS are hermetically sealed articles. [The SOCl2 is converted to SO2 and sulfur chlorides. 0000003034 00000 n 5.3 Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Toxic exposure to fumes of Thionyl Chloride reacting with water may result in a delayed pulmonary response (longer than two weeks) of bronchiolitis Obliterans-inflammation of the bronchioles. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. * Breathing Thionyl Chloride can irritate the lungs causing coughing and/or shortness of breath. * Exposure to Thionyl Chloride can irritate the nose and throat. CDC is not responsible for Section 508 compliance (accessibility) on other federal or private website. 27 0 obj<>stream Hazard statement(s ) H302 Harmful if swallowed. Lithium-Thionyl Chloride (Li-SOCl2) Battery 1/6 Document Number: RD-ER-201501-001 Issued date: 3 January 2015 EVE Energy Co., Ltd Safety and Reliability Lab MATERIAL SAFETY… UN1836 Thionyl chloride, Hazard class: 8; Labels: 8-Corrosive material. SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. 0000006724 00000 n 169 F (76.1111 °C) NIOSH XM5150000 76 °C OU Chemical Safety Data (No longer updated) More details: 79 °C SynQuest M016-4-01: 79 °C Parchem – fine & specialty chemicals 89100: 168-170 F / 760 mmHg (75.5556-76.6667 °C / 760 mmHg) Wikidata Q409171 169 F / 760 mmHg (76.1111 °C / 760 mmHg) Wikidata Q409171 79 °C Sigma-Aldrich SIAL-18438: 75.7 °C / 760 mmHg Kaye & Laby (No longer … H314 Causes severe skin burns and eye damage. Purification Methods: Crude SOCl2 can be freed from sulfuryl chloride, sulfur monochloride and sulfur dichloride by refluxing it with sulfur and then fractionally distilling twice. +T�Ϭzz���[��\�M�It��Gh��|����,Bj��,|8�=��o�j� ��J��TW�SU@2�"���։nl�ZU�YxF���Q*�J�%��Ԓ��d��!�H� ��k��Lת$M�2_��г�U_Z U�@=���,��T��ӥ4��{Xf���ܲ�� PM:�7�#�ҬUQ�z�����" Thionyl chloride is an inorganic acid chloride mainly used as a reagent to prepare carboxylic acid chlorides from carboxylic acids. The mixture of thionyl chloride with ethyl acetate in the presence of zinc or iron metal results in an explosively hazardous mixture. Chronic –Overexposure can cause symptoms of non-fibrotic lung injury. 0000001570 00000 n Hazard statement (s) H302 Harmful if swallowed. Thionyl chloride should be stored in glass containers at ambient temperature and protected from moisture. Because all cells and batteries are defined as “articles”,they are exempt from the requirements of the Hazard Communications Standard. Thionyl Chloride: 1.635 Not applicable unless there is exposure to an electrolyte. 0000001761 00000 n Thionyl chlorideRevision Date 14-Feb-2020. [Note: Fumes form when exposed to moist air. Shop a large selection of products and learn more about Thionyl chloride, 99%, Alfa Aesar. 0000006028 00000 n Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 … * Thionyl Chloride is a CORROSIVE CHEMICAL and contact can severely irritate and burn the skin and eyes with possible eye damage. Chronic: Chronic exposure may cause effects similar to those of acute exposure. Certain batteries contain small amounts of thionyl chloride, but it's impractical to extract it. xref 0000000892 00000 n Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. 0000004033 00000 n Thionyl chloride is sold by various chemical suppliers, but due to its hazards it's generally not available to the amateur chemist. GHS SDS requirements and classification criteria do … H314 Causes severe skin burns and eye damage. 5.2 Special hazards arising from the substance or mixture Sulphur oxides, Hydrogen chloride gas Container explosion may occur under fire conditions. Its sale is regulated in many places. 0000021119 00000 n 0000001391 00000 n Not applicable unless there is exposure to an electrolyte. 0000002795 00000 n Violently reacts with water to liberate hydrochloric acid and sulfur dioxide [NFPA 10th ed. Precautionary statement(s ) P261 Avoid breathing vapours. National Institute for Occupational Safety and Health (NIOSH) Recommended Exposure Level TO THIONYL CHLORIDE-air: ceiling concentration 1 ppm: NIOSH* DHHS #92-100,1992: National Occupational Exposure Survey 1983 The Saft primary Lithium-Thionyl chloride batteries do not contain toxic materials. Binary mixtures of these components seem stable, while ternary mixtures result in spontaneously violent reactions. 0000005178 00000 n Fires may be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire. Important additional information about respirator selection, Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride, Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide. Precautionary statement (s) Prevention. 0000004730 00000 n 0000002751 00000 n the larynx and bronchi, chemical pneumonitis, and pulmonary edema. ], inhalation, ingestion, skin and/or eye contact, irritation eyes, skin, mucous membrane; eye, skin burns, Centers for Disease Control and Prevention. * Thionyl Chloride is a CORROSIVE CHEMICAL and contact can severely irritate and burn the skin and eyes with possible eye damage. Decisions that inherently pose a risk of injury or a hazard to human beings or property should not be made on the basis of this information. 1991]. Causes gastrointestinal/digestive tract burns. 0000007494 00000 n Solubility in other solvents Thionyl Chloride: Decomposes violently on contact with water. Lithium Thionyl Chloride Battery. 24 0 obj<> endobj [Note: Reacts violently with water to form sulfur dioxide & hydrogen chloride. Toxic exposure to fumes of Thionyl chloride reacting with water may result in delayed pulmonary response, bronchiolitis Oblitereans(inflammmation of the bronchioles). Suitable products for Thionyl chloride SOCl 2. Safety hazards have ranged from mild venting of toxic materials to violent explosions and fires. CDC twenty four seven. 0000003279 00000 n Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. Buy Thionyl Chloride GHS Labels from HCL & clearly identify hazards. Thionyl chloride solution 2.0 M in methylene chloride; CAS Number: 7719-09-7; Linear Formula: Cl2OS; find Sigma-Aldrich-293121 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich. * Thionyl Chloride can affect you when breathed in. Thionyl chloride is widely used to convert carboxylic acids and alcohols to the corresponding acyl chlorides and alkyl chlorides respectively via an internal nucleophilic substitution. Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. Thionyl chloride is listed on schedule 3 of the Chemical Weapons Convention and ordering large amounts may draw attention of the authorities. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. Partition coefficient: n None known -octanol/water Not applicable unless there is exposure to an electrolyte. [Note: Fumes form when exposed to moist air.] 0000005516 00000 n * Exposure to Thionyl Chloride can irritate the nose and throat. Thionyl chloride is an inorganic compound with the chemical formula SOCl2. Application Thionyl chloride may be used in the following processes: • To facilitate the synthesis of indenones from 3-hydroxyindanones via dehydroxylation. Harmful if swallowed. %%EOF Do not eat, drink or smoke when using this product. OSHA HazCom compliant labels are made with chemical & solvent resistant materials. Ingestion: Corrosive. 0000002717 00000 n trailer 0000001174 00000 n 0000003355 00000 n May cause respiratory irritation. P270 Do not eat, drink or smoke when using this product. For this reason, improper handling of the battery could lead to distortion, leakage, overheating, explosion, fire, or generation of irritating/corrosive gases and cause human injury or equipment trouble. thionyl chloride Thionyl dichloride thionyl dichoride; Thionyl dichloride; Show more chemical information. Shipping Requirements: Lithium metal batteries and cells are subject to the shipping requirements and exceptions under 49 CFR 173.185. You will be subject to the destination website's privacy policy when you follow the link. 0000020267 00000 n H332 Harmful if inhaled. H331 Toxic if inhaled. 0000005773 00000 n endstream endobj 25 0 obj<. Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. HAZARD SUMMARY * Thionyl Chloride can affect you when breathed in. Inhalation of sulfuryl chloride or thionyl chloride vapors can result in pulmonary edema. startxref Thionyl chloride is an inorganic compound with the chemical formula S O Cl 2.It is a moderately volatile colourless liquid with an unpleasant acrid odour. Thionyl chloride. 0000002248 00000 n Please strictly observe safety instructions. Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide. 24 29 This is a high energy density sealed battery containing (Lithium) and (Thionyl Chloride) materials. 0 Signs and symtoms of exposure :Eye and mucous membrane irritation. The internal component (thionyl chloride) is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1920.1200. OSHA Status: The internal component (thionyl chloride) is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1920.1200. ], Water, acids, alkalis, ammonia, chloryl perchlorate 12 - ECOLOGICAL INFORMATION When properly used or disposed, the Lithium-Thionyl chloride batteries do not present environmental hazard. 500g. 0000008902 00000 n Precautionary Statements. Wash face, hands and any exposed skin thoroughly after handling. 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